Pigment in western Iberian schematic rock art : an analytical approach
Part of : Mediterranean archaeology & archaeometry : international journal ; Vol.15, No.1, 2015, pages 163-175
Issue:
Pages:
163-175
Abstract:
This paper explores the processes involved in the production of prehistoric paintings using inorganic pigmentation. The focus for discussion involves a number of rock-shelter sites that contain rock art within the western part of the Iberian Peninsula, with particular reference to the sites that contain Schematic rock art. A direct date cannot be obtained on rock art that is made with inorganic pigments. However, sampling and subsequent analysis has clearly shown that pigments were produced using tried and tested recipes that involved the use of sometimes organic binders. This paper will explore the chemical and mineralogical qualities of sampled pigments from a selected number of sites within Spain and Portugal and suggest that pigmentation was more than just applying paint to rock.
Subject:
Subject (LC):
Keywords:
painting, pigmentation, ochre, Raman spectroscopy, schematic rock art
References (1):
- Almeida, F., Angelucci, D., Gameiro, C. Correia, J. & Pereira, T., (2004) Novos dados para o Paleolítico Superior final da Estremadura Portuguesa: resultados preliminares dos trabalhos arqueológicos de 1997-2003 na Lapa dos Coelhos (Casais Martanes, Torres Novas). Promontoria, Ano 2, nº 2, Faro, p.157-192.Balbín Behrmann, R., De Alcolea González, J.J. & González, M.A., (2003) El macizo de Ardines, Ribadesella, España. Un lugar mayor del arte paleolítico europeo. In R.Balbín Behrmann, de, P. Bueno Ramírez (Eds.), Primer Symposium Internacional de Arte Prehistórico de Ribadesella. Associación Cultural Amigos de Ribadesella, pp. 91–151.Bikiaris D., Daniilia, S., Sotiropoulou, O., Katsimbiti, E., Pavlidou A.P., Moutsatsou, C. Y. & Chryssoulakis, Y., (2000) Ochre-differentiation through micro-Raman and mi-cro-FTIR spectroscopies: application on wall paintings at Meteora and Mount Athos, Greece. Spectrochimica Acta. Part A 56, 3–18.Breuil, H., (1929) Les roches peintes de Zarza (Badajoz). IPEK. Jahrbuch für Prahistorisehe und Etnographische Kunst, V, pp. 14-30.Burgio, L.; Clark, R. J. H., (2001) Library of FT-Raman spectra of pigments, minerals, pigment media and varnishes, and supplement to existing library of Raman spectra of pigments with visible excitation. Acta Spectrochimica, Part A, 57, 1491-1521.Collado, H. & García, J.J., (eds.) (2005) Arte rupestre en el Parque Natural de Monfragüe: el sector oriental. Corpus de Arte Rupestre en Extremadura, Vol. I. Consejería de Cultura.Collado, H., (2006) Arte rupestre del valle del Guadiana. El conjunto de grabados del Molino Manzánez (Alconchel - Cheles, Badajoz). Memorias de Odiana, No. 4. EDIA.Collado, H., (2009) Propuesta para la clasificación funcional y cronológica del arte rupes-tre esquemático a partir del modelo extremeño. Estudios de Prehistoria y Arqueolo-gía en homenaje a Pilar Acosta, Universidad de Sevilla, pp. 89-108.Dams, M., (1984) Les Pientures Rupestres du Levant Espagnol. Paris: Picard.Derksen, G.C.H., Lelyveld, G.P., Van Beek, T.A., Capelle, A. & De Garoot, Æ., (2004) Phy-tochemichel Analysis,15, pp. 397–406.Elias, M., Chartier, C., Prévot, G., Garay, H., & Vignaud, C., (2006) The colour of ochres explained by their composition. Materials Science and Engineering B, 127, 70–80.Faria, D.L.A. & Lopes, F.N., (2007) Heated goethite and natural hematite: can Raman spectroscopy be used to differentiate them? Vib. Spectrosc.; 45: 17–21.Fortea, P.F.J. & Hoyos, M., (1999) La table ronde de Colombres et les études de protection et conservation en Asturies réalisées de 1992 à 1996, Bulletin de la Société Préhisto-rique Ariége-Pyrénées, 54: 235-242.Fuller, C., (1988) Natural Colored Iron Oxide Pigments, In P. Lewis (ed.)Pigment Hand-book, 2nd Edition. New York: John Wiley & Sons. pp. 281–6.García Arranz, J.J., Collado Giraldo, H. and Nash, G.H. (eds.), (2012) El problema “Levanti-no”: Arte rupestre postpaleolitico en le Peninsula Ibérica. Budapest: Archaeolingua.Gialanella, S., Girardi, F., Ischia, G., Lonardelli, I., Mattarelli, M., Montagna, M., (2010) On the Goethite to hematite phase transformation. J. Therm. Anal Calorim. 102, 867-873 DOI:10.1007/s1973-010-0756-2.Gialanella, S., Belli, R., Dalmeri, G., Lonardelli, I., Mattarelli, M. Montagna, M. & Toniutti, L., (2011) Artificial or natural origin of hematite-based red pigments. Archaeometry 53, 5, 950–962.Gomes, H., Rosina, P., Martins, A. & Oosterbeek, L., (2013) Pinturas Rupestres: Matérias-Primas, Técnicas e Gestão do Território. Estudos Do Quaternário, 9, Apeq, Braga, pp. 45-55.Hernanz, A., Ruiz-Lopez, J., Gavira-Vallejo M., Martin, S. & Gavrilenkod, E., (2009) Raman Microscopy of prehistoric rock paintings from the Hoz de Vicente, Minglanilla, Cuenca, Spain 1394–1399.Hovers, E., Ilani, S., Bar-Yosef, O. & Vandermeersch, B., (2003) An early case of colour symbolism: ochre used by modern humans in Qafzeh Cave, Current Anthropology, 44(4), 491–522.Hradil, D., Grygar, T., Hradilova J. & Bezdic P., (2003) Clay and iron oxide pigments in the history of painting. Clay Science 22, pp. 223– 236.Iriarte, E., Foyo, A., Sánchez, M.A. Tomillo, C. & Setién J., (2009) The Origin and Geo-chemical Characterization of Red Ochres from the Tito Bustillo and Monte Cas-tillo Caves (Northern Spain). Archaeometry 51, issue 2 231-251.Legodi M. A. & de Waal D., (2007). The preparation of magnetite, goethite, hematite and maghemite of pigment quality from mill scale iron waste, Dyes and Pigments, 74, pp. 161-168.Marean, C. W., Bar-Matthews, M., Bertnachez, J., Fisher, E., Goldberg, P., Herries, A. I. R., Jacobs, Z., Jerardino, A., Karkanas, P., Minichillo, T., Nilssen, P. J., Thompson, E., Watts, I. & Williams, H. M. (2007) Early human use of marine resources and pigment in South Africa during the Middle Pleistocene. Nature, 449, 905–8.Marshall, L., Williams, J. R., Almond, M. J., Atkinson, S.D.M., Cook, S. R., Matthews, W. &Mortimore, J. L., (2005) Analysis of ochres from Clearwell Caves: the role of particle size in determining colour. Spectrochimica Acta, Part A, 61, 233–241.Martins, A., (2007) Arte Rupestre no concelho de Torres Novas: a Lapa dos Coelhos, Nova Augusta - Revista de Cultura, nº 19, Ed. Município de Torres Novas, pp. 377-388.Martins, A., (2013a) Arte Esquemático en Portugal: los abrigos con pinturas del Macizo Calcáreo Extremeno, coord. Julián Martínez García y Mauro S. Hernández Pérez, Arte Rupestre Esquemático en la Península Ibérica – II Congreso 2010, Ayuntamiento de Vélez-Blanco, pp. 317-323.Martins, A., (2013b) A Pintura Rupestre Esquemática em Portugal: muitos sítios, mesmas pessoas?, coord. José Arnaud, Andrea Martins e César Neves, Arqueologia em Portugal – 150 anos, Associação dos Arqueólogos Portugueses, pp. 495-505.Martins, A., Rodrigues, A. & Garcia Díez, M., (2004) Arte esquemática do Maciço Calcário Estremanho: Abrigo do Lapedo I e Lapa dos Coelhos, Arkeos 15 – Perspectivas em diálogo: Arte Rupestre, Pré-história e Património, coord. Ana Rosa Cruz e Luiz Oosterbeek, CEIPHAR, pp. 15 – 27.Mas, M., Jorge A., Gavilán, B., Solís, M., Parra E. &Pérez P.P. (2013) Minateda rock shelters (Albacete) and post-palaeolithic art of the Mediterranean Basin in Spain: pigments, surfaces and patinas. Journal of Archaeological Science 40, 4635-4647.Mastrotheodoros, G., Beltsios, K.G. & Zacharias, N., (2010). Assessment of the production of antiquity pigments through experimental treatment of ochres and other iron based precursors. Mediterranean Archaeology and Archaeometry 10 (1), pp. 37–59.Michaelsen, P., Ebersole, T.W., Smith, N.W. & Biro, P. (2000) Australian ice age rock art may depict Earth’s oldest recordings of Shamanistic rituals. Mankind Quarterly, 41(2) 131–146.Montagner, C., Sanches, D., Pedroso, J., Melo, M.J. & Vilarigues, M., (2013) Ochres and earths: Matrix and chromophores characterization of 19th and 20th century artist materials. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 103, 409–416.Mortimore, J. L., Marshall, L.-J. R., Hollins, M. P. & Matthews, W., (2004) Analysis of red and yellow ochre samples from Clearwell Caves and Çatalhöyük by vibrational spectroscopy and other techniques. Spectrochimica Acta, Part A, 60, pp. 1179–88.Nash, G.H. (2008) Northern European hunter/fisher/gatherer and Spanish Levantine rock-art: A study in performance, cosmology and belief. Trondheim: NTNU.Navarro Gascón, J. V., (2003) Nuevos resultados obtenidos en el estudio de pigmentos y posibles materias colorantes de las pinturas de la Cueva de Tito Bustillo, in Pri-mer symposium internacional de arte prehistórico de Ribadesella:el arte prehistórico des-de los inicios del diglo XXI (eds. R. de Balbín Behrmann and P. Bueno Ramírez), pp. 173–84.Nuevo M. J., Sánchez A. M., Oliveira, C. & Oliveira, J., (2012) In situ energy dispersive X-ray fluorescence analysis of rock art pigments from the ‘Abrigo dos Gaivões’ and ‘Igreja dos Mouros’ caves (Portugal). X-ray Spectroscopy Journal. 41, 1, 1-5.Oosterbeeck, L., (2002) Le culte de l’eau dans le Alto Ribatejo, Portugal. Arkeos, No. 12, pp. 227-256.Ortiz Macías, M., (1998) Pintura rupestre esquemática al sur de la comarca de Mérida. Serie Arqueológica nº 17. Diputación de Badajoz.Peresani, M., Vanhaeren, M., Quaggiotto, E., Queffelec, A. & D’errico, F., (2013) An Oche-red Fossil Marine Shell From the Mousterian of Fumane Cave, Italy. PLOS ONE, 8, 7. E68572.Pike, A.W.G., Hoffmann, D. L., Garcia-Diez, M., Pettitt, P. B., Alcolea, J., De Balbin, R., Gonzalez-Sainz, C., De Las Heras, C., Lasheras, J. A., Montes, R. & Zilhao, J., (2012) U-Series Dating of Palaeolithic Art in 11 Caves in Spain. Science 336 (6087), 1409–1413.Pomiès, M. P. & Menu, M., (1999). Red palaeolithic pigments: natural hematite or heated goethite?, Archaeometry, 41 (2), pp. 275-285.Prinsloo, L. B. W., Meiklejohn, I. & Hall, K., (2008) The first Raman spectroscopic study of San rock art in the Ukhahlamba Drakensberg Park, South Africa, Journal of Ra-man Spectroscopy, 39: 646–654.Salomon, H., Vignaud, C., Coquinot, Y., Beck, L., Stringer, C., Strivay, D., & D’errico, F., (2012) Selection and Heating of Colouring Materials in the Mousterian Level of Es-Skhul (c. 100 000 Years Bp, Mount Carmel, Israel). Archaeometry 54, 4, pp. 698–722.Sanchidrian, J.L., (2001) Manual de arte prehistórico, Ariel Prehistoria, pp. 339-484Thomas, A., (1980) Colours from the Earth. New York: Van Nostrand Reinhold.Vanhaeren, M. & D‘Errico F., (2002) The Body Ornaments Associated with the Burial. In J. Zilhão J and E. Trinkaus (eds.), Portrait of the artist as a child: The Gravettian Hu-man Skeleton from the Abrigo do Lagar Velho and its Archaeological Context. Lisboa, Instituto Português de Arqueologia. Trabalhos de Arqueologia, 22: 154-186.Viniegra, V., (1929) El arte rupestre en la provincia de Badajoz. Cornisa de la Calderita, Sierra de la Zarza. Revista del centro de estudios extremeños, Vol. III, pp. 63-82.Whitley, D.S., (2001) Handbook of Rock art Research. Walnut Creek: AltaMira Press.Wreschner, E. E., (1980) Red Ochre and Human Evolution: A Case for Discussion. Current Anthropology, Vol. 21: 631–644.Zilhão, J., (2007) The emergence of ornaments and art: An archaeological perspective on the origins of behavioural modernity. Journal of Archaeological Research 15: 1–54.Zilhão, J., Angelucci D.E., Badal-García E., D´Errico F., & Daniel F. (2010) Symbolic use of marine shells and mineral pigments by Iberian Neanderthals. Proceedings of the National Academy of Sciences, 107: 1023-1028.